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[Ni(HF2)(3-Clpy)(4)]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F center dot center dot center dot H center dot center dot center dot F- Bridges in a One-Dimensional Polymeric Chain
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[Ni(HF2)(3-Clpy)(4)]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F center dot center dot center dot H center dot center dot center dot F- Bridges in a One-Dimensional Polymeric Chain

Jamie L. Manson, Adora G. Baldwin, Brian L. Scott, Jesper Bendix, Rico E. Del Sesto, Paul A. Goddard, Yoshimitsu Kohama, Hope E. Tran, Saman Ghannadzadeh, John Singleton, …
Inorganic chemistry, Vol.51(14), pp.7520-7528
07/16/2012
DOI: https://doi.org/10.1021/ic300111k
PMID: 22746404

Abstract and subjects

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
[Ni(HF2)(3-ClPY)(4)]BF4 (py = Pyridine) is a simple one-dimensional (ID) coordination polymer composed of compressed NiN4F2 octahedra that form chains with bridging HF2- ligands. In spite of significant distortion of the HF2- bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J(FHF) = 4.86 K.

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