Back
Chromatographic separation of selenium and arsenic: A potential Se-72/As-72 generator
Journal article   Peer reviewed

Chromatographic separation of selenium and arsenic: A potential Se-72/As-72 generator

Donald E. Wycoff, Matthew D. Gott, Anthony J. DeGraffenreid, Ryan P. Morrow, Nebiat Sisay, Mary F. Embree, Beau Ballard, Michael E. Fassbender, Cathy S. Cutler, Alan R. Ketring, …
JOURNAL OF CHROMATOGRAPHY A, Vol.1340, pp.109-114
05/02/2014
DOI: https://doi.org/10.1016/j.chroma.2014.03.033
PMID: 24679827

Abstract and subjects

Biochemical Research Methods Biochemistry & Molecular Biology Chemistry Chemistry, Analytical Life Sciences & Biomedicine Physical Sciences Science & Technology
An anion exchange method was developed to separate selenium and arsenic for potential utility in a Se-72/As-72 generator. The separation of the daughter As-72 from the Se-72 parent is based on the relative acid-base behavior of the two oxo-anions in their highest oxidation states. At pH 1.5, selenate is retained on strongly basic anion exchange resin as HSeO4- and SeO42-, while neutral arsenic acid, H3AsO4, is eluted. (C) 2014 Elsevier B.V. All rights reserved.

Metrics

2 Record Views

Details