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Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)(2), ThCl4(1,4-dioxane)(2) and ThCl4(THF)(3.5) using commercially available and inexpensive starting materials
Journal article   Peer reviewed

Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)(2), ThCl4(1,4-dioxane)(2) and ThCl4(THF)(3.5) using commercially available and inexpensive starting materials

Thibault Cantat, Brian L. Scott and Jaqueline L. Kiplinger
Chemical communications (Cambridge, England), Vol.46(6), pp.919-921
01/01/2010
DOI: https://doi.org/10.1039/b923558b
PMID: 20107650

Abstract and subjects

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Anhydrous thorium tetrachloride complexes ThCl4(DME)(2), ThCl4(1,4-dioxane)(2), and ThCl4(THF)(3.5) have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(IV) halide, alkoxide, amide and organometallic compounds.

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